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Расчёт коэффициентов активности для НС1 5 страница
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| Продолжение таблицы
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| C6H4O2
| п-бензохинон
| тв
| –
| –184514
| –83680
| 162, 75
| 132, 63
| 22, 59
| 372, 37
| –
| 73–298
| –
| –
| –
|
| C6H6O
| фенол
| г
| –
| –94140
| –34392
| 328, 44
| 99, 16
| –
| –
| –
| –
| 694, 4
| 60, 5
| 0, 244
|
|
| –“–
| тв
| –3063524
| –155854
| –40752
| 140, 76
| 133, 05
| 23, 01
| 287, 85
| 217, 56
| 78–296
| –
| –
| –
|
| C6H6O2
| гидрохинон
| тв
| –2860600
| –362962
| –207024
| 140, 16
| 142, 25
| 8, 368
| 426, 76
| –
| 187–445
| –
| –
| –
|
| C6H12O
| циклогесанол
| ж
| –3726688
| –349154
| –134180
| 199, 57
| 208, 90
| –
| –
| –
| –
| –
| –
| –
|
| C6H14O
| н-гексиловый
| г
| –
| –330201
| –
| –
| –
| –
| –
| –
| –
| –611
|
| –
|
|
| спирт
| ж
| –
| –384802
| –157109
| 287, 02
| 232, 50
| –
| –
| –
| –
| –
| –
| –
|
| C7H6O2
| бензойная к-та
| тв
| –3226700
| –384551
| –245600
| 170, 70
| 145, 18
| –
| –
| –
| –
| –
| –
| –
|
| C7H16O
| н-гептиловый спирт
| ж
| –4622901
| –406768
| –149996
| 325, 93
| –
| –
| –
| –
| –
|
| 29, 4
| –
| C8H4O3
| фталевая к-та
| тв
| –3226115
| –781905
| –591282
| 207, 94
| 188, 28
| –
| –
| –
| –
| –
| –
| –
| C8H18O
| н-октиловый
| г
| –
| –375137
| –
| –
| –
| –
| –
| –
| –
|
| 26, 5
| –
|
|
| спирт
| ж
| –
| –455504
| –143720
| 351, 45
| –
| –
| –
| –
| –
| –
| –
| –
|
| C12H10O4
| хингидрон
| тв
| –
| –82801
| –322962
| 325, 93
| 276, 98
| –
| –
| –
| –
| –
| –
| –
|
| C16H34O
| цетиловый
| ж
| –
| –634838
| –96106
| 606, 68
| –
| –
| –
| –
| –
| –
| –
| –
|
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| спирт
| тв
| –10479079
| –683749
| –98826
| 451, 87
| –
| –
| –
| –
| –
| –
| –
| –
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| Галогенсодержащие соединения
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| CF4
| четырехфто-ристый углерод
| г
| –
| –912112
| –867242
| 261, 41
| 61, 12
| –
| –
| –
| –
| 227, 2
| 41, 4
| –
|
|
| четыреххло- ристый углерод
| г
| –186188
| –106692
| –64015
| 309, 40
| 83, 51
| 97, 65
| 9, 62
| –
| 298–1000
| 556, 4
| 45, 0
| –
|
|
| –“–
| ж
| –156063
| –139372
| –68617
| 214, 43
| 131, 75
| 97, 98
| 153, 55
| –
| 273–330
| –
| –
| –
| CClF3
| трифторхлор-метан
| г
| –
| –715464
| –674879
| 285, 47
| 66, 81
| –
| –
| –
| –
| 302, 0
| 39, 0
| 0, 278
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| Продолжение таблицы
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| CCl2F2
| дифторди-хлорметан
| г
| –
| –468608
| –429467
| 300, 57
| 72, 29
| –
| –
| –
| –
| 384, 7
| 89, 6
| 0, 273
| |
| CCl3F
| фтортрихлор-метан
| г
| –
| –292880
|
| 309, 44
| 77, 86
| –
| –
| –
| –
| 471, 2
| 43, 2
| 0, 277
| |
| CH3Cl
| хлористый метил
| г
| –687012
| –86395
| –62592
| 233, 46
| 40, 71
| 14, 90
| 96, 23
| –31, 51
| 273–800
| 416, 3
| 65, 9
| 0, 276
| |
| CH3F
| иодистый метил
| г
| –810440(ж)
|
|
| 355, 64
| 44, 14
| 17, 17
| 102, 45
| –40, 72
| 298–600
| 528, 2
| 72, 7
| –
| |
| CH2Cl2
| дихлорметан
| г
| –446851
| –87864
|
| 270, 62
| 51, 37
| 33, 47
| 65, 27
| –
| 273–800
| 510, 2
| 60, 0
| –
| |
| CHCl3
| хлороформ
| г
| –402710
| –100416
| –66944
| 296, 47
| 65, 81
| 29, 50
| 148, 94
| –90, 70
| 273–800
| 536, 6
|
| 0, 294
| |
|
| –“–
| ж
| –335556
| –131796
| –71546
| 202, 92
| 116, 31
| –
| –
| –
| –
| –
| –
| –
| |
| C2H4Br2
| 1, 2-дибромэтан
| г
| –
| –38911
| –10543
| 329, 74
| –
| –
| –
| –
| –
|
| 70, 6
| –
| |
|
| –“–
| ж
| –
| –80751
| –20668
| 223, 30
| 13, 602
| –
| –
| –
| –
| –
| –
| –
| | C2H4Cl2
| 1, 2-дихлорэтан
| г
| –1133864
| –130959
| –75312
| 308, 82
| 79, 49
| –
| –
| –
| –
| 561, 0
|
| 0, 259
| |
|
| –“–
| ж
| –
| –165686
| –84516
| 208, 53
| –
| –
| –
| –
| –
| –
| –
| –
| |
| C2H5Cl
| хлористый этил
| г
| –1325072
| –107528
| –55479
| 275, 30
| 62, 34
| –
| –
| –
| –
| 460, 4
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| –
| |
| C3H7Cl
| хлористый изопропил
| г
| –
| –144599
| –62425
| 310, 03
| 87, 57
| –
| –
| –
| –
| 503, 2
| 45, 2
| –
| |
| C6Cl6
| гексахлор-бензол
| тв
| –
| –130959
|
| 268, 61
| 201, 29
| –
| –
| –
| –
| –
| –
| –
| |
| C6Cl5OH
| пентахлор-фенол
| тв
| –
| –295390
| –145929
| 251, 91
| 201, 96
| –
| –
| –
| –
| –
| –
| –
| |
| C6H5F
| фторбензол
| г
| –
| –110792
| –63178
| 302, 62
| 94, 43
| –
| –
| –
| –
| 560, 1
| 44, 9
| 0, 263
| |
|
| –“–
| ж
| –
| –145394
| –69036
| 238, 22
| –
| –
| –
| –
| –
| –
| –
| –
| | C6H5Cl
| хлорбензол
| г
| –
|
|
| 313, 21
| 97, 06
| –
| –
| –
| –
| 632, 4
| 44, 6
| 0, 265
| |
| –“–
| ж
| –
|
|
| 197, 48
| 150, 20
| –
| –
| –
| –
| –
| –
| –
| | |
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| Продолжение таблицы
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| | C6H5Br
| бромбензол
| г
| –
|
|
| 325, 34
| 99, 70
| –
| –
| –
| –
| 670, 2
| 44, 6
| 0, 263
| |
|
| –“–
| ж
| –
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| 207, 94
| 155, 51
| –
| –
| –
| –
| –
| –
| –
| |
| C6H5Br
| иодобензол
| г
| –
| –
| –
| 334, 09
| 100, 75
| –
| –
| –
| –
| 721, 2
| 44, 6
| 0, 265
| |
|
| –“–
| ж
| –
|
| –
| 205, 43
| 158, 78
| –
| –
| –
| –
| –
| –
| –
| |
| Азот- и серусодержащие соединения
| |
| CH3NO2
| нитрометан
| г
| –
| –74726
| –6945
| 275, 01
| –
| –
| –
| –
| –
| 588, 2
| 62, 3
| 0, 223
| |
|
| –“–
| ж
| –708769
| –113302
| –14560
| 171, 96
| 105, 85
| –
| –
| –
| –
| –
| –
| –
| |
| CH3NO3
| метилнитрат
| г
| –
| –123009
| –
| –
| –
| –
| –
| –
| –
| –
| –
| –
| |
|
| –“–
| ж
| –
| –155644
| –39748
| 216, 98
| 157, 19
| –
| –
| –
| –
| –
| –
| –
| |
| CH4N2O
| мочевина
| тв
| –634294
| –333188
| –197150
| 104, 6
| 93, 13
| –
| –
| –
| –
| –
| –
| –
| |
| CH5N
| метиламин
| г
| –1071522
| –28032
|
| 241, 54
| 53, 97
| –
| –
| –
| –
| 430, 1
| 73, 6
| –
| | C2N2
| дициан
| г
| –
|
|
| 242, 08
| 56, 90
| –
| –
| –
| –
| 400, 1
| 50, 0
| –
| |
| C2H3N
| цианистый метил
| г
| –
|
|
| 242, 71
| 51, 88
| –
| –
| –
| –
| –
| –
| –
| |
|
| –“–
| ж
| –1265241
|
|
| 144, 34
| –
| –
| –
| –
| –
| –
| –
| –
| |
| C2H5NO2
| глицин (гликоколь)
| тв
| –981148
| –528439
| –370702
| 109, 20
| 100, 41
| –
| –
| –
| –
| –
| –
| –
| |
| C2H7N
| диметиламин
| г
| –
| –27614
|
| 273, 21
| –
| –
| –
| –
| –
| 456, 2
| 55, 5
| 0, 280
| |
|
| –“–
| ж
| –1743472
| –58157
|
| 182, 33
| 69, 37
| –
| –
| –
| –
| –
| –
| –
| |
| C3H6N6
| меланин
| г
| –
| –71671
|
| 149, 07
| –
| –
| –
| –
| –
| –
| –
| –
| |
| C3H9N
| тримети-ламин
| ж
| –2421113
|
|
| 208, 44
| 133, 88
| –
| –
| –
| –
| 433, 3
| 40, 2
| 0, 287
| | C4H4S
| тиофен
| г
| –
|
|
| 278, 86
| 72, 88
| –
| –
| –
| –
| 580, 1
| 56, 2
| –
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| Продолжение таблицы
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| C4H4S
| тиофен
| ж
| –
|
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| 181, 16
| –
| –
| –
| –
| –
| –
| –
| –
| |
| C4H9N3O2
| креатин
| тв
| –
| –537309
| –265056
| 189, 53
| –
| –
| –
| –
| –
| –
| –
| –
| |
| C5H5N
| пиридин
| г
| –
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| 282, 79
| 78, 11
| –
| –
| –
| –
| 617, 4
| 60, 0
| –
| |
|
| –“–
| ж
| –
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| 181, 16
| –
| –
| –
| –
| –
| –
| –
| –
| |
| C5H6S
| фурфурило-вый спирт
| ж
| –
| –276269
| –154222
| 215, 89
| –
| –
| –
| –
| –
| –
| –
| –
| |
| C5H6S
| 2-метил-тиофен
| г
| –
|
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| 319, 08
| 95, 39
| –
| –
| –
| –
| –
| –
| –
| |
|
| –“–
| ж
| –
|
|
| 218, 48
| –
| –
| –
| –
| –
| –
| –
| –
| |
| C5H6S
| 3-метил-тиофен
| г
| –
|
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| 321, 29
| 94, 85
| –
| –
| –
| –
| –
| –
| –
| |
|
| –“–
| ж
| –
|
|
| 218, 32
| –
| –
| –
| –
| –
| –
| –
| –
| |
| C6H5NO2
| нитробензол
| г
| –
|
| –
| –
| –
| –
| –
| –
| –
| –
| –
| –
| |
| –“–
| ж
| –3092812
|
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| 224, 26
| 185, 77
| –
| –
| –
| –
| –
| –
| –
| |
| C6H6N2O2
| о-нитро-анилин
| тв
| –
| –14434
|
| 176, 14
| 126, 77
| –
| –
| –
| –
| –
| –
| –
| |
| C6H6N2O2
| м-нитро-анилин
| тв
| –
| –18660
|
| 176, 14
| 168, 19
| –
| –
| –
| –
| –
| –
| –
| |
| C6H6N2O2
| п-нитро-анилин
| тв
| –
| –41505
|
| 176, 14
| 169, 03
| –
| –
| –
| –
| –
| –
| –
| |
| C6H6S
| тиофенол
| г
| –
|
|
| 336, 85
| 104, 89
| –
| –
| –
| –
| –
| –
| –
| |
|
| –“–
| ж
| –
|
|
| 222, 79
| 173, 21
| –
| –
| –
| –
| –
| –
| –
| |
| C6H7O
| анилин
| г
| –3340015
|
| –
| –
| –
| –
| –
| –
| –
| 699, 2
| 52, 4
| 0, 25
| |
|
| –“–
| ж
| –3396152
|
|
| 191, 62
| 199, 57
| 338, 27
| –1068, 59
| 2022, 12
| 278–348
| –
| –
| –
| |
| C7H11NO
| ε -капролактам
| тв
| –
| –32823
| –95060
| 168, 61
| –
| –
| –
| –
| –
| –
| –
| –
| | C7H13NO
| энантолактам
| тв
| –
| –347355
| –79914
| 189, 95
| –
| –
| –
| –
| –
| –
| –
| –
| | C9H7N
| хинолин
| ж
| –
| –156063
|
| 217, 15
| –
| –
| –
| –
| –
| –
| –
| –
| |
|
|
| Ионы в водных растворах
|
|
| Таблица
| Ион
| ,
кДж× моль–1
| ,
Дж× моль–1× К–1
| ,
кДж× моль–1
| Ион
| ,
кДж× моль–1
| ,
Дж× моль–1× К–1
| ,
кДж× моль–1
|
|
|
|
|
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|
|
| Ag+
| 105, 75
| 73, 39
| 77, 10
| CH3COO-
| –485, 64
| 87, 58
| –369, 37
|
| Al3+
| –529, 69
| –301, 25
| –489, 80
| CN-
| 150, 62
| 96, 45
| 171, 58
|
| AsO43-
| –890, 06
| –167, 28
| –648, 93
| CNO-
| –145, 90
| 101, 13
| –96, 07
|
| Ba2+
| –524, 05
| 8, 79
| –547, 50
| CNS-
| 74, 27
| 146, 05
| 89, 96
|
| Br-
| –121, 50
| 82, 84
| –104, 04
| CO32-
| –676, 64
| –56, 04
| –527, 60
|
| BrO3-
| –83, 68
| 163, 18
| 1, 53
| C2O42-
| –824, 25
| 51, 04
| –674, 86
| Ca2+
| –542, 66
| –55, 23
| –552, 70
| H2PO4-
| –1296, 29
| 90, 37
| –1130, 34
|
| Cd2+
| –75, 31
| –70, 92
| –77, 65
| Hg2+
| 173, 47
| –25, 15
| 164, 68
|
| Cl-
| –167, 07
| 56, 74
| –131, 29
| Hg22+
| 171, 75
| 82, 17
| 153, 60
|
| ClO-
| –110, 04
| 32, 97
| –36, 61
| I-
| –56, 90
| 106, 69
| –51, 94
|
| ClO2-
| –66, 53
| 101, 25
| 17, 12
| I3-
| –51, 46
| 239, 32
| –51, 42
|
| ClO3-
| –95, 56
| 164, 43
| –0, 19
| IO3-
| –220, 52
| 117, 78
| –127, 16
|
| ClO4-
| –123, 60
| 183, 68
| –3, 40
| K+
| –252, 17
| 101, 04
| –282, 62
|
| Co2+
| –56, 61
| –110, 46
| –53, 64
| Li+
| –278, 45
| 11, 30
| –292, 86
|
| Co3+
| 94, 14
| –285, 01
| –129, 70
| Mg2+
| –461, 75
| –119, 66
| –455, 24
| Cr2+
| –138, 91
| 41, 87
| –183, 26
| Mn2+
| –220, 50
| –66, 94
| –229, 91
|
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| Продолжение таблицы
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| |
| Cr3+
| –235, 98
| –215, 48
| –223, 06
| MnO4-
| –533, 04
| 196, 23
| –440, 28
| |
| CrO42-
| –875, 42
| 46, 02
| –720, 91
| NH4+
| –132, 80
| 112, 84
| –79, 52
| |
| Cr2O72-
| –1490, 93
| 270, 39
| –1295, 62
| NO2-
| –104, 60
| 139, 85
| –37, 16
| |
| Cs+
| –258, 04
| 132, 84
| –291, 96
| NO3-
| –207, 38
| 146, 94
| –111, 49
| |
| Cu+
| 72, 80
| 44, 35
| 50, 00
| Na+
| –240, 30
| 58, 41
| –261, 90
| |
| Cu2+
| 66, 94
| –92, 72
| 65, 56
| Ni2+
| –53, 14
| –126, 05
| –45, 56
| |
| CuNH32+
| –36, 86
| 17, 90
| 15, 76
| OH-
| –230, 02
| –10, 71
| –157, 35
| |
| Cu(NH3)2+
| –151, 04
| 263, 59
| –65, 37
| PO43-
| –1277, 38
| –220, 29
| –1018, 81
| |
| Cu(NH3)22+
| –140, 21
| 117, 74
| –30, 50
| Pb2+
| (–1, 18)
| –24, 32
| (11, 82)
| | Cu(NH3)32+
| –244, 01
| 204, 24
| –73, 18
| PtCl42-
| –500, 82
| 125, 64
| –354, 01
| |
| Cu(NH3)42+
| –346, 52
| 280, 50
| –111, 51
| PtCl62-
| –669, 44
| 223, 43
| –485, 31
| |
| Cu(NH3)52+
| –448, 23
| 309, 47
| –134, 64
| Ra2+
| –529, 69
| 28, 87
| (–555, 99)
| |
| F-
| –333, 84
| –14, 02
| –279, 99
| Rb+
| –251, 12
| 120, 46
| –283, 76
| |
| Fe2+
| –87, 86
| –113, 39
| –84, 88
| S2-
| 32, 64
| –14, 52
| 85, 40
| |
| Fe3+
| –47, 70
| –293, 30
| –10, 53
| SO32-
| –638, 27
| –38, 28
| –486, 73
| |
| H+
|
|
|
| SO42-
| –909, 26
| 18, 20
| –743, 99
| | HCOO-
| –426, 22
| 90, 81
| –351, 54
| SiF62-
| –2396, 51
| 125, 94
| –2208, 25
| | HCO3-
| –691, 28
| 92, 57
| –586, 56
| Sn2+
| –10, 23
| –25, 26
| –26, 24
| |
| Ион
| ,
кДж× моль–1
| ,
Дж× моль–1× К–1
| ,
кДж× моль–1
| Ион
| ,
кДж× моль–1
| ,
Дж× моль–1× К–1
| ,
кДж× моль–1
| |
| HC2O4-
| –818, 18
| 117, 03
| –688, 47
| Sr2+
| –545, 51
| –26, 36
| –560, 97
| |
| HF2-
| –660, 65
| 67, 78
| –581, 52
| Tl+
| 5, 52
| 126, 20
| –32, 43
| |
| HPO32-
| –969, 01
| (16, 81)
| –811, 70
| Tl3+
| 201, 25
| –176, 92
| 214, 76
| |
| HPO42-
| –1292, 14
| –33, 47
| –1089, 28
| U3+
| –514, 63
| –125, 52
| –520, 59
| |
| HS-
| –17, 57
| 62, 76
| 12, 15
| U4+
| –590, 15
| –382, 62
| –538, 91
| |
| HSO3-
| –627, 98
| 132, 38
| –527, 32
| UO22+
| –1018, 66
| –89, 68
| –954, 71
| |
| HSO4-
| –887, 77
| 127, 97
| –755, 23
| Zn2+
| –153, 64
| –110, 62
| –147, 16
| |
| H2PO3-
| –969, 43
| 79, 50
| –830, 81
|
|
|
|
| |
| Ионы в жидком аммиаке
| |
| Ag+
| 108, 8
| 96, 2
| 73, 6
| K+
| –169, 4
| 89, 5
| –196, 6
| | Br-
| –246, 9
| –126, 8
| –167, 4
| Li+
| –205, 0
| 33, 5
| –225, 9
| |
| Ca2+
| –418, 4
| –87, 9
| –418, 0
| NC2-
| –49, 4
| –
| –
| |
| Cl-
| –274, 9
| –126, 8
| –184, 5
| NH2-
| 42, 3
| –41, 8
| 141, 8
| |
| ClO3-
| –199, 6
| 62, 8
| –74, 1
| NH4+
| –67, 4
| 103, 3
| –11, 3
| |
| Cs+
| –163, 2
| 121, 3
| –193, 7
| NO3-
| –324, 7
| –20, 9
| –178, 6
| |
| H+
| 0, 0
| 0, 0
| 0, 0
| Na+
| –159, 4
| 63, 2
| –182, 4
| |
| Hg2+
| 189, 1
| 146, 4
| 129, 3
| Pb2+
| 87, 9
| 46, 0
| 54, 4
| | I-
| –189, 5
| –104, 6
| –121, 3
| Rb+
| –163, 2
| 121, 3
| –196, 2
| | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | |
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